Coherent-state representation of reduced density matrices of correlated electronic systems

Citation
Mf. Schulz et al., Coherent-state representation of reduced density matrices of correlated electronic systems, CHEM P LETT, 327(1-2), 2000, pp. 29-37
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
327
Issue
1-2
Year of publication
2000
Pages
29 - 37
Database
ISI
SICI code
0009-2614(20000901)327:1-2<29:CRORDM>2.0.ZU;2-L
Abstract
The one-particle reduced density matrix of correlated electronic systems is computed by expressing the many-electron wavefunction as a superpositon of generalized coherent states, each representing a single Slater determinant . This representation could be used for developing a density matrix functio nal theory. The sensitivity of the density matrix to the parameters is demo nstrated. (C) 2000 Published by Elsevier Science B.V.