Chemical ionization of 1-olefins (C-15-C-18) by CH5+, C2H5+, and C3H5+ in an ion-trap type of mass spectrometer

Authors
Tsuji, M Tanaka, Y Arikawa, T Nishimura, Y
Citation
M. Tsuji et al., Chemical ionization of 1-olefins (C-15-C-18) by CH5+, C2H5+, and C3H5+ in an ion-trap type of mass spectrometer, CHEM LETT, (8), 2000, pp. 892-893
Citations number
4
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
2000
Pages
892 - 893
Database
ISI
SICI code
0366-7022(20000805):8<892:CIO1(B>2.0.ZU;2-E
Abstract
Chemical ionization of 1-olefins /1-CxH2x: x = 15-18) by the CH5+, C2H5+ an d C3H5+ ions has been studied using an ion-trap type of GC/MS under a react ant-ion-selected mode. In all the reactions. CyH2y+1+ (y = 3-x) alkyl and C yH2y-1+ (y = 3-x) alkenyl ions were observed with maximum intensities at y = 3-5 for CyH2y+1+ and at y=7 or 8 for CyH2y-1+.