One-dimensional S = 1 ferromagnetic chain formed by a square Ni2S2 motif in Ni(qt)(2) (qt = quinoline-8-thiolate)

Authors
Miyake, T Ishida, T Hashizume, D Iwasaki, F Nogami, T
Citation
T. Miyake et al., One-dimensional S = 1 ferromagnetic chain formed by a square Ni2S2 motif in Ni(qt)(2) (qt = quinoline-8-thiolate), CHEM LETT, (8), 2000, pp. 952-953
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
2000
Pages
952 - 953
Database
ISI
SICI code
0366-7022(20000805):8<952:OS=1FC>2.0.ZU;2-P
Abstract
X-ray crystallographic analysis of the title complex reveals that nickel(II ) ions are arranged to form a one-dimensional chain structure with double t hiolate-bridges. The Ni-S-Ni angle is 94.3 degrees. Magnetic susceptibility measurements indicate that the nickel S = 1 spins are ferromagnetically co upled within a chain.