Face selectivity in the borohydride reduction of 4-eq,6-ax-diaryl-5-azaadamantan-2-ones

Authors
Jimenez-Cruz, F Cetina, R Rios-Olivares, H
Citation
F. Jimenez-cruz et al., Face selectivity in the borohydride reduction of 4-eq,6-ax-diaryl-5-azaadamantan-2-ones, CHEM LETT, (8), 2000, pp. 956-957
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
2000
Pages
956 - 957
Database
ISI
SICI code
0366-7022(20000805):8<956:FSITBR>2.0.ZU;2-Z
Abstract
The highly preferential attack at the rn face in the reduction with sodium borohydride of 4-eq,6-ax-diaryl-5-azaadamantan-2-ones in methanol is descri bed. Steric and electronic effects are involved.