Geometrical model of the structure of the heterocomplex compound [Cr(OCN2H4)(6)](3+)[Co(DH)(2)(NO2)(2)](3)(-) center dot 2H(2)O

Authors
Rau, VG Rau, TF Lebedev, GO Kurkutova, EN
Citation
Vg. Rau et al., Geometrical model of the structure of the heterocomplex compound [Cr(OCN2H4)(6)](3+)[Co(DH)(2)(NO2)(2)](3)(-) center dot 2H(2)O, CRYSTALLO R, 45(4), 2000, pp. 595-600
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTALLOGRAPHY REPORTS
ISSN journal
10637745 → ACNP
Volume
45
Issue
4
Year of publication
2000
Pages
595 - 600
Database
ISI
SICI code
1063-7745(200007/08)45:4<595:GMOTSO>2.0.ZU;2-G
Abstract
The structural organization of the new heterocomplex compound with carbamid e has been considered on the basis of division of the crystal space into Di richlet polyhedra of the system of Delone points (centers of the complex io ns). It is demonstrated that the coordination numbers for all domains (Diri chlet domains) of the complex ions in the structure obey the "rule of fourt een," whereas the polyhedra providing the structural organization of the cr ystal are distorted Fedorov cuboctahedra. (C) 2000 MAIK "Nauka/Interperiodi ca".