Isovaleric acid (3-methylbutanoic acid) was found to be a major consti
tuent of the inflorescence odour of Senecio articulatus and contribute
s to its fetid smell. Other important constituents were linalool and i
ts oxides. Production of isovaleric acid from a single capitulum was f
ound to be greater during the day, when new florets opened, than durin
g the night, whereas the terpenoids showed less temporal variation. Th
e odour is distinct from that of sapromyophilous plants whose odours m
imic dung and carrion but, in producing isovaleric acid, shows similar
ities to other potentially fly pollinated flowers with unpleasant odou
rs. (C) 1997 Elsevier Science Ltd. All rights reserved.