G. Burillo et al., Studies on salts of amine-containing polymers with benzoic acids. III. Poly(N, N-dimethylaminoethyl methacrylate-g-polyethylene) with benzoic acids, J APPL POLY, 78(5), 2000, pp. 972-978
Poly(N,N-dimethylaminoethyl methacrylate) [poly(DMAEMA)] was grafted onto a
commercial polyethylene film by means of gamma-irradiation, and the grafte
d films were reacted with various liquid-crystal-forming benzoic acids. Whe
n polymeric salts consisting only of poly(DMAEMA) and the benzoic acids wer
e heated, dissociation of salts was observed, but with poly(DMAEMA) grafted
onto polyethylene films, salt dissociation or crystallization of dissociat
ed acids could be avoided, and interesting morphologies, including liquid-c
rystal phases, were observed for the systems of benzoic acids-poly(DMAEMA-g
-polyethylene). (C) 2000 John Wiley & Sons, Inc.