Citation
E. Anselmi et al., Perfluoroalkylation of aliphatic thiols in the presence of sodium hydroxymethanesulfinate, J FLUORINE, 105(1), 2000, pp. 41-44
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139
→ ACNP
Volume
105
Issue
1
Year of publication
2000
Pages
41 - 44
Database
ISI
SICI code
0022-1139(200008)105:1<41:POATIT>2.0.ZU;2-5
Abstract
Direct perfluoroalkylation of aliphatic thiols was pet-formed in the presen
ce of sodium hydroxymethanesulfinate (Rongalite). Reaction of mercaptoalkan
oic esters with trifluoromethyl bromide gave the corresponding trifluoromet
hylthio ethers. Condensation of alkane dithiols with perfluoroalkyl iodides
led mainly to fluorinated dithioethers. These alkylation reactions are int
erpreted as occurring via in situ formation of dialkyldisulfides. (C) 2000
Elsevier Science S.A. All rights reserved.