Reaction of perfluoralkylhydrazines with iminoesters - Synthesis of perfluoroalkyl-3-aminothienopyrimidinones and perfluoralkyl-1,2,4-triazin-6-ones

Authors
Kammoun, M Khemakhem, AM Hajjem, B
Citation
M. Kammoun et al., Reaction of perfluoralkylhydrazines with iminoesters - Synthesis of perfluoroalkyl-3-aminothienopyrimidinones and perfluoralkyl-1,2,4-triazin-6-ones, J FLUORINE, 105(1), 2000, pp. 83-86
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
105
Issue
1
Year of publication
2000
Pages
83 - 86
Database
ISI
SICI code
0022-1139(200008)105:1<83:ROPWI->2.0.ZU;2-I
Abstract
Treatment of N-(2-methoxycarbonylthienyl) 1, N-(3-ethoxycarbonyl)-4,5,6,7-t etrahydrobenzothienyl 2 and N-ethoxycarbonylmethyl 3 imidates with perfluor oalkylated hydrazines yields perfluoroalkyl-3-amino[3,2-d]4(3H)thienopyrimi dinones 4, perfluoroalkyl-3-amino-2-methyl-5,6,7,8-tetrahydrobenzo[2,3-d]4( 3H)thienopyrimidinones 5 and perfluoro-alkyl-1,2,4-triazin-6-ones 6. The pr oducts obtained gave information on the mechanism of cyclization. (C) 2000 Elsevier Science S.A. All rights reserved.