Synthesis and structural studies of Ti-Ru polymetallic systems

Authors
Le Gendre, P Richard, P Moise, C
Citation
P. Le Gendre et al., Synthesis and structural studies of Ti-Ru polymetallic systems, J ORGMET CH, 605(2), 2000, pp. 151-156
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
605
Issue
2
Year of publication
2000
Pages
151 - 156
Database
ISI
SICI code
0022-328X(20000707)605:2<151:SASSOT>2.0.ZU;2-J
Abstract
The reaction of the titanocene monophosphines 1 and 2 with the dimer [(p-cy mene)RuCl2](2) give the heterobimetallic compounds (p-cymene)[(eta(5)-C5H4) (mu-eta(5):eta(1)-C5H4PPh2)TiCl2]RuCl2 and (p-cymene)[(eta(5)-C5H4)(mu-eta( 5):eta(1)-C5H4CH2CH2PPh2)TiCl2]RuCl2, respectively. Both structures have be en confirmed by X-ray diffraction. By using same procedure, the synthesis o f a trimetallic complex Ru-Ti-Ru has been achieved. (C) 2000 Elsevier Scien ce S.A. All rights reserved.