Synthesis and characterization of dialkylgallium (dialkylindium) complexesof N-salicylidene 2-aminopyridine and N-salicylidene 2-methoxyaniline: crystal structure of dimethyl[N-salicylidene 2-aminopyridine]gallium

Reaction of trimethylgallium (trimethylindium) and triethylgallium (triethy lindium) with N-salicylidene 2-aminopyridine or N-salicylidene 2-methoxyani line in benzene solution yields seven intramolecular coordinated Group 13 m etal Schiff-base complexes. All complexes obtained were characterized by el emental analysis, H-1-NMR, IR and mass spectrometry. The structure of dimet hyl[N-salicylidene 2-aminopyridine]gallium (1) was determined by X-ray sing le crystal analysis. The Ga atom is four coordinate in the structure. Photo luminescent emission spectra of complexes dimethyl[N-salicylidene 2-aminopy ridine]gallium (1), diethyl[N-salicylidene 2-aminopyridine]gallium (3), die thyl[N-salicylidene 2-aminopyridine]indium (4) and dimethyl[N-salicylidene 2-methoxylaniline]gallium (5) were measured. The maximum emission wavelengt h is between 503 and 511 nm, respectively on radiation by UV light. (C) 200 0 Elsevier Science S.A. All rights reserved.