Synthesis of N,N-bis(silyloxy)enamines with a functionalized double bond

Authors
Dilman, AD Tishkov, AA Lyapkalo, IM Ioffe, SL Kachala, VV Strelenko, YA Tartakovsky, VA
Citation
Ad. Dilman et al., Synthesis of N,N-bis(silyloxy)enamines with a functionalized double bond, J CHEM S P1, (17), 2000, pp. 2926-2929
Citations number
24
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14704358 → ACNP
Issue
17
Year of publication
2000
Pages
2926 - 2929
Database
ISI
SICI code
1470-4358(2000):17<2926:SONWAF>2.0.ZU;2-D
Abstract
The general method for the double silylation of alpha- or beta-functionaliz ed aliphatic nitro compounds 1 leading to regio- and stereoselective format ion of N,N-bis(silyloxy)enamines 3 with a functionalized double bond is ela borated. The configuration of obtained products is determined by NMR spectr oscopy.