The suitability of Fourier transform infrared photoacoustic spectroscopy (F
TIR-PAS) for analysing potato chips was investigated. The functional groups
, vibration modes and intensities corresponding to frequencies related to m
oisture, fat and protein in PA spectra were labelled. Oxidation experiments
were carried out by heating home-made chips in a convection oven at 80 deg
rees C. Changes in chemical groups related to fat and oh were observed visu
ally and statistically. Spectral data were analysed using PCA correlation a
nd a linear discriminant analysis technique with squared Mahalanobis distan
ce metric to estimate the extent of oxidation. Results showed that deterior
ation indeed could be monitored by photoacoustic spectroscopy. Depth profil
e analysis of the samples showed that a spectral difference in the fat, moi
sture and protein bands at different layers exists. Results demonstrated th
at FTIR-PAS with its depth-profiling capability could be used for qualitati
ve analysis. (C) 2000 Society of Chemical Industry.