Kinetics and mechanism of the furan peroxide formation in the reaction of furfural with hydrogen peroxide in the presence or absence of sodium molybdate

Authors
Grunskaya, EP Badovskaya, LA Kaklyugina, TY Poskonin, VV
Citation
Ep. Grunskaya et al., Kinetics and mechanism of the furan peroxide formation in the reaction of furfural with hydrogen peroxide in the presence or absence of sodium molybdate, KINET CATAL, 41(4), 2000, pp. 447-450
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
41
Issue
4
Year of publication
2000
Pages
447 - 450
Database
ISI
SICI code
0023-1584(200007/08)41:4<447:KAMOTF>2.0.ZU;2-O
Abstract
The kinetics of the initial stage of the furfural reaction with hydrogen pe roxide was studied in water in the presence of Na2MoO4 and in n-butanol wit hout a catalyst. The mechanisms of furfural conversion in the Na2MoO4-H2O2 system and oxidation by hydrogen peroxide in the absence of sodium molybdat e are discussed. Based on kinetic studies, the mechanism of furan peroxide formation is proposed.