Formation of vanadia-titania oxide catalysts

Authors
Zenkovets, GA Kryukova, GN Tsybulya, SV Al'kaeva, EM Andrushkevich, TV Lapina, OB Burgina, EB Dovlitova, LS Malakhov, VV Litvak, GS
Citation
Ga. Zenkovets et al., Formation of vanadia-titania oxide catalysts, KINET CATAL, 41(4), 2000, pp. 572-583
Citations number
80
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
41
Issue
4
Year of publication
2000
Pages
572 - 583
Database
ISI
SICI code
0023-1584(200007/08)41:4<572:FOVOC>2.0.ZU;2-B
Abstract
The formation of vanadia-titania catalysts was studied with a complex of ph ysicochemical methods. The use of highly dispersed anatase with a defect st ructure results in the formation of coherent boundaries of coalescence of t he V2O5 and TiO2 crystallites with the ratio V : Ti = 1 : 1 in a wide range of vanadium and titanium concentrations. The catalysts containing coherent boundaries are active and selective in P-picoline oxidation to nicotinic a cid.