Monoorganotin-polyoxometal-compounds: II. Isolation and structural characterization of compounds containing the unprecedented monoorganotin molybdateanion [(RSn)(4)(MoO4)(4)O(OH)(3)](-)

Authors
Kastner, G Reuter, H
Citation
G. Kastner et H. Reuter, Monoorganotin-polyoxometal-compounds: II. Isolation and structural characterization of compounds containing the unprecedented monoorganotin molybdateanion [(RSn)(4)(MoO4)(4)O(OH)(3)](-), MAIN GR MET, 23(7), 2000, pp. 383-388
Citations number
16
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
23
Issue
7
Year of publication
2000
Pages
383 - 388
Database
ISI
SICI code
0792-1241(2000)23:7<383:MIIASC>2.0.ZU;2-C
Abstract
The syntheses, molecular and crystal structures of [((PrSn)-Pr-i)(12)O-14(O H)(6)] [((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](2) . 6DMSO (1) under bar and [(( PrSn)-Pr-i)(12)O-14(OH)(6)] [((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](2) . 10DMF (2) under bar are described. Both compounds contain the until now unknown [ ((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](-) cage ion, the first example of monoor ganotin molybdates with isolated anions. It is composed of two groups of tw o edge sharing {(PrSnO5)-Pr-i} octahedra linked by four mu(3)-{MoO4} tetrah edra. Inside this cage ion a mu(2)-OH ...mu(2)-O hydrogen bond between the two groups of {(PrSnO4)-Pr-i(OH)} double octahedra is observed.