A theoretical study of the mechanism of oxidative methane addition to the palladium ethylenediphosphine complex [H2P(CH2)(2)PH2]Pd with considerationfor tunnelling

Authors
Mamaev, VM Gloriozov, IP Simonyan, VV Babin, YV Lemenovskii, DA
Citation
Vm. Mamaev et al., A theoretical study of the mechanism of oxidative methane addition to the palladium ethylenediphosphine complex [H2P(CH2)(2)PH2]Pd with considerationfor tunnelling, MENDELEEV C, (4), 2000, pp. 155-156A
Citations number
13
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
4
Year of publication
2000
Pages
155 - 156A
Database
ISI
SICI code
0959-9436(2000):4<155:ATSOTM>2.0.ZU;2-B
Abstract
In terms of the reaction-path Hamiltonian formalism, tunnelling has been fo und to make the major contribution to the rate constant of methane activati on by the title complex at T < 270 K.