Pt films on alumina substrates, both in their as-received and annealed stat
es, have been extensively characterized by slow positron implantation spect
roscopy (SPIS). Bulk Pt samples have been investigated by conventional posi
tron annihilation spectroscopy (PAS) as well as by SPIS. A variety of state
-of-the-art theoretical calculations have been performed to aid the interpr
etation of experimental findings. The research shows that a re-interpretati
on of earlier defect studies of bulk Pt by PAS is required in order to achi
eve a satisfactory agreement with the present experimental findings and the
ory.