Effect of shear stress field on the sizes of macromolecules in polymer solutions and blends

Citation
Sa. Vshivkov et Ev. Rusinova, Effect of shear stress field on the sizes of macromolecules in polymer solutions and blends, POLYM SCI A, 42(6), 2000, pp. 699-703
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER SCIENCE SERIES A
ISSN journal
0965545X → ACNP
Volume
42
Issue
6
Year of publication
2000
Pages
699 - 703
Database
ISI
SICI code
0965-545X(200006)42:6<699:EOSSFO>2.0.ZU;2-R
Abstract
Equations describing relationship between the binodal and liquidus curve sh ifts, induced by a shear stress field, and the macromolecular stretching co efficient are proposed for the polymer-polymer and polymer-solvent systems. The concentration dependences of the shear flow-induced variation of the m acromolecular dimensions are calculated for the systems with crystalline an d amorphous phase separation.