Transformations of titanium dihydride

Authors
Shilov, AL Dobrokhotova, ZV Padurets, LN
Citation
Al. Shilov et al., Transformations of titanium dihydride, RUSS J IN C, 45(8), 2000, pp. 1160-1163
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
8
Year of publication
2000
Pages
1160 - 1163
Database
ISI
SICI code
0036-0236(200008)45:8<1160:TOTD>2.0.ZU;2-W
Abstract
Hydrides TiH1.99, TiH1.89, and TiH1.60 and deuteride TiD1.99 were synthesiz ed and characterized by DTA and DSC in the temperature range 80-500 K. The results were compared to available H-1 NMR data for TiH1.99. In addition to the known fct-fcc (gamma'-gamma) transformation at 290-300 K, a new second -order transition was found in TiH2-x at ca. 450 K.