Simulation of phase diagrams for water-salt systems with solid solutions

Citation
Py. Azimov et Ag. Shtukenberg, Simulation of phase diagrams for water-salt systems with solid solutions, RUSS J IN C, 45(8), 2000, pp. 1302-1309
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
8
Year of publication
2000
Pages
1302 - 1309
Database
ISI
SICI code
0036-0236(200008)45:8<1302:SOPDFW>2.0.ZU;2-E
Abstract
A semiempirical model for the description of phase relations in water-salt systems with continuous solid solutions is presented. The model was derived from a thermodynamic analysis of equilibria in mixed crystals and aqueous solution. The phase diagram of the system is shown to depend on the propert ies of a solid solution and the solubility ratio of the components. The res ults of calculations in terms of the model are compared to experimental dat a on water-salt systems with solid solutions.