Binuclear thiocyanate platinum(II) complexes: Cationic complexes

Authors
Gel'fman, MI Salishcheva, OV
Citation
Mi. Gel'Fman et Ov. Salishcheva, Binuclear thiocyanate platinum(II) complexes: Cationic complexes, RUSS J IN C, 45(5), 2000, pp. 707-709
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
5
Year of publication
2000
Pages
707 - 709
Database
ISI
SICI code
0036-0236(200005)45:5<707:BTPCCC>2.0.ZU;2-Q
Abstract
The cis-diaminediacidoplatinum(II) complexes PtL2(SCN)(2) (L = NH3, en/2) r eact with PtL1L2Cl2 (L-1, L-2 = NH3, en/2, dimethyl sulfoxide (DMSO), dieth yl sulfide) to produce cationic binuclear complexes in which the platinum a toms are bridged by two thiocyanate ligands. Convenient methods of analysis of binuclear complexes for SCN, Cl, and Pt were developed based on prelimi nary destruction of the bridges by ethylenediamine and thiourea.