Formation of heterometal ruthenium complexes with nonferrous metals in nitrite systems

Citation
Va. Emel'Yanov et al., Formation of heterometal ruthenium complexes with nonferrous metals in nitrite systems, RUSS J IN C, 45(5), 2000, pp. 728-733
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
5
Year of publication
2000
Pages
728 - 733
Database
ISI
SICI code
0036-0236(200005)45:5<728:FOHRCW>2.0.ZU;2-7
Abstract
The fact of interaction of ruthenium nitrite complexes with copper(II) and nickel(II) salts in aqueous solutions was established by NMR, EPR, and elec tronic spectroscopy. The formation of heterometal complexes was assumed. Th is accounts for the fact that ruthenium is accompanied by these metals duri ng refinement according to the nitrite technology.