Effect of mechanochemical activation on synthesis of metalloorganosiloxanes

Authors
Shapkin, NP Kapustina, AA Talashkevich, EA
Citation
Np. Shapkin et al., Effect of mechanochemical activation on synthesis of metalloorganosiloxanes, RUSS J IN C, 45(4), 2000, pp. 601-604
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
4
Year of publication
2000
Pages
601 - 604
Database
ISI
SICI code
0036-0236(200004)45:4<601:EOMAOS>2.0.ZU;2-Z
Abstract
Mechanochemical interaction of monosodium phenylsilanetriol salts with MCl3 where M = Fe or Cr leads to the formation of ferrophenyl- or chromophenyls iloxanes. The influence of conditions of mechanochemical treatment and of t he nature of reagents on the course of the process was studied. The reactio n products were studied by IR spectroscopy, electron microscopy, and X-ray powder diffraction. The specific surface area of the samples was determined .