Interaction of hydrochloric acid solution of palladium with trioctylamine and a fluorinated graphite intercalation compound with trioctylamine

Authors
Tatarchuk, VV Paasonen, VM Korda, TM Shubin, YV
Citation
Vv. Tatarchuk et al., Interaction of hydrochloric acid solution of palladium with trioctylamine and a fluorinated graphite intercalation compound with trioctylamine, RUSS J IN C, 45(4), 2000, pp. 656-661
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
4
Year of publication
2000
Pages
656 - 661
Database
ISI
SICI code
0036-0236(200004)45:4<656:IOHASO>2.0.ZU;2-O
Abstract
Extraction of palladium by individual trioctylamine (TOA) and a fluorinated graphite intercalation compound (FGIC) containing 50 wt % TOA is studied. IR and Raman spectroscopy, spectrophotometry, X-ray powder diffraction, the rmogravimetry, and chemical analysis were used to show that (TOAH)(2)[PdCl4 ], [Pd(TOA)2Cl(2)], and (TOAH)(2)[Pd2Cl6] complexes result from a reaction of hydrochloric solutions of palladium(II) with TOA in FGIC, as in extracti on with free TOA. Effective constants of extraction of a mixture of mononuc lear species are found to be log K* = 4.27 +/- 0.09 (TOA) and 4.16 +/- 0.08 (TOA-FGIC).