Khayanolides A and B, new rearranged phragmalin limonoid antifeedants fromKhaya senegalensis

Citation
M. Nakatani et al., Khayanolides A and B, new rearranged phragmalin limonoid antifeedants fromKhaya senegalensis, TETRAHEDR L, 41(33), 2000, pp. 6473-6477
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
33
Year of publication
2000
Pages
6473 - 6477
Database
ISI
SICI code
0040-4039(20000812)41:33<6473:KAABNR>2.0.ZU;2-O
Abstract
Khayanolides A and B, two new rearranged phragmalin limonoids, were isolate d as insect antifeedants together-with two known rings B,D-seco compounds, methyl angolensate and its 6-hydroxy derivative from the ether extract of t he stem bark of Khaya senegalensis. The structure of the new compounds was elucidated by spectroscopic means and the absolute structure of khayanolide A was established by X-ray analysis and CD study. The antifeedant activity is also reported. (C) 2000 Elsevier Science Ltd. All rights reserved.