First synthesis of a alpha-trifluoromethyl allenol ether via the Julia-Lythgoe process

Authors
Yoshimatsu, M Hibino, M
Citation
M. Yoshimatsu et M. Hibino, First synthesis of a alpha-trifluoromethyl allenol ether via the Julia-Lythgoe process, CHEM PHARM, 48(9), 2000, pp. 1395-1398
Citations number
23
Categorie Soggetti
Chemistry & Analysis
Journal title
CHEMICAL & PHARMACEUTICAL BULLETIN
ISSN journal
00092363 → ACNP
Volume
48
Issue
9
Year of publication
2000
Pages
1395 - 1398
Database
ISI
SICI code
0009-2363(200009)48:9<1395:FSOAAA>2.0.ZU;2-N
Abstract
alpha-Trifluromethyl allenol ethers 9a-e were prepared in moderate to good yields by the Julia-Lythgoe process using beta-ethoxy-beta-trifluoronmethyl vinylic sulfone 3, Several reactions of 9c were examined to give alpha,bet a-unsaturated trifluoromethyl ketone derivatives 11 and 12.