S. Santra et al., Excited-state intramolecular proton transfer in the anionic species of 2-(2 '-acetamidophenyl) benzimidazole in aqueous medium, CHEM P LETT, 327(3-4), 2000, pp. 230-237
An excited-stare intramolecular proton transfer (ESIPT) process has been ob
served in the anionic species of 2,-(2'-acetamidophenyl)benzimidazole (2-AM
PBI). Dual fluorescence is observed in the case of monoanionic species. The
presence of different monoanionic species has been characterized by means
of steady-state and time-resolved fluorescene spectroscopy, as well as usin
g AM1 semi-empirical quantum-mechanical calculations. The present study rev
ealed that the presence of an acetyl group plays a vital role in the stabil
ity of different ionic and neutral species and in changes in their ground (
S-0) and excited singlet state (S-1) acid-base properties with respect to 2
-(2'-aminophenyl)benzimidazole (2-APBI). (C) 2000 Elsevier Science B.V. All
rights reserved.