Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes

Authors
Pan, HZ Liu, CQ Cao, M Xie, P Zhang, RB Lin, YH Chung, NTS
Citation
Hz. Pan et al., Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes, CHIN J POLY, 18(5), 2000, pp. 459-463
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
CHINESE JOURNAL OF POLYMER SCIENCE
ISSN journal
02567679 → ACNP
Volume
18
Issue
5
Year of publication
2000
Pages
459 - 463
Database
ISI
SICI code
0256-7679(200009)18:5<459:SONHMW>2.0.ZU;2-L
Abstract
Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by " stepwise coupling polymerization". The molecular weight of CP-T is as high as 1.7 x 10(5). It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with ma ny nucleophilic reagents to generate new ladderlike reactive polysilsesquio xanes, which can be used as potential precursors in the synthesis of functi onal ladderlike polymers.