Carbon implantation into silicon, at beam energies from 30 to 60 keV and at
ion doses of 3.0 x 10(17) to 1.5 x 10(18) cm(-2) with a metal vapor vacuum
are ion, was performed to form SiC layers at substrate temperatures below
400 degrees C. It was found that the substrate temperature for the conversi
on of amorphous phase SiC (alpha-SiC) into cubic phase SiC (beta-SiC) durin
g the carbon implantation, is much lower than the conversion temperature (a
pprox. 900 degrees C) of alpha-SiC into beta-SiC induced by the post-anneal
ing. The feature of the low substrate temperature of the metal vapor vacuum
are (MEVVA) ion source is thought to be due to the ion-beam-induced crysta
llization (IBIC) effect. The profile of the carbon content, which is of Gau
ssian shape similar to the data of TRIM-90 calculation, is associated well
with the distribution of the ratio of [relative amount of beta-SiC/relative
amount of alpha-SiC] in the SiC layers. Moreover, in the carbon rich regio
n the higher degree of crystallization is attributed to the higher beta-SiC
fraction. (C) 2000 Elsevier Science S.A. All rights reserved.