Isotope dilution inductively coupled plasma quadrupole mass spectrometry in connection with a chromatographic separation for ultra trace determinations of platinum group elements (Pt, Pd, Ru, Ir) in environmental samples

An isotope dilution inductively coupled plasma quadrupole mass spectrometri c (ID-ICP-QMS) method was developed for the simultaneous determination of t he platinum group elements Pt, Pd, Ru, and Lr in environmental samples. Spi ke solutions, enriched with the isotopes Pt-194, (108)pd, Ru-99, and Ir-191 , were used for the isotope dilution step. Interfering elements were elimin ated by chromatographic separation using an anion-exchange resin. Samples w ere dissolved with aqua regia in a high pressure asher. Additional dissolut ion of possible silicate portions by hydrofluoric acid was usually not nece ssary. Detection limits of 0.15 ng g(-1), 0.075 ng g(-1), and 0.015 ng g(-1 ) were achieved for Pt, Pd, Ru, and Lr, respectively, using sample weights of only 0.2 g. The reliability of the ID-ICP-QMS method was demonstrated by analyzing a Canadian geological reference material and by participating in an interlaboratory study for the determination of platinum and palladium i n a homogenized road dust sample. Surface soil, sampled at different distan ces from a highway, showed concentrations in the range of 0.1-87 ng g(-1). An exponential decrease of the platinum and palladium concentration with in creasing distance and a small anthropogenic contribution to the natural bac kground concentration of ruthenium and iridium was found in these samples.