Citation
M. Nozawa et al., Total synthesis of (+)-galanolactone, HETEROCYCLE, 53(8), 2000, pp. 1811
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414
→ ACNP
Volume
53
Issue
8
Year of publication
2000
Database
ISI
SICI code
0385-5414(20000801)53:8<1811:TSO(>2.0.ZU;2-L
Abstract
Regioselective monobenzylation of the chemoenzymatically prepared chiral de
calin-type diol ((8aS)-6) via the benzylidene acetal ((8aS)-11) afforded th
e primary alcohol((8aS)-7), from which total synthesis of(+)-galanolactone
(1) was achieved and formal syntheses of (+)-(E)-8 beta(17), 12-labddiene-1
5, 16-dial ((+)-3) and (+)-coronarin E (4) were carried out.