Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T-1 -> S-0 intersystem crossing in jet-cooled thiophosgene, Cl2CS
Dc. Moule et al., Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T-1 -> S-0 intersystem crossing in jet-cooled thiophosgene, Cl2CS, J CHEM PHYS, 113(10), 2000, pp. 3937-3940
Two-color optical-optical double resonance studies of the T-1-->S-0 intersy
stem crossing in jet-cooled thiophosgene indicate that rotational symmetry
strongly influences the efficiency of an intersystem crossing in symmetric
molecules with low degrees of rotational excitation. (C) 2000 American Inst
itute of Physics. [S0021-9606(00)01734-7].