Isomeric structures and energies of H-n(+) clusters (n=13, 15, and 17)

Ab initio calculations have been performed for the H-n(+) clusters (n=3-17; odd) at Moller-Plesset second order (MP2)/6-311G(mp), Moller-Plesset compl ete fourth order (MP4)/6-311G(mp), and coupled-cluster single-double-triple [CCSD(T)/6-311G(1p)] levels of calculations. Such hydrogen clusters are co nstituted by an H-3(+) core in which H-2 units are bound. In order to under stand the features of these bindings, enthalpy and entropy variations upon cluster formation, binding energies, and charge distributions have been com puted, and a molecular orbital analysis, based on localized orbital, was pe rformed. Our results show that the way the first three H-2 units bind to th e H-3(+) core is fundamentally different from the others, providing an expl anation for the binding energies observed for these molecules. For the H-13 (+), H-15(+), and H-17(+) clusters, the way in which the external H-2 units are distributed around the H-3(+) plane leads to the formation of differen t isomers with very close energies, but with a rotational barrier large eno ugh to inhibit the interconversions. (C) 2000 American Institute of Physics . [S0021-9606(00)31434-9].