In recent years the idea of electromagnetically induced transparency in ato
mic systems using a microwave coupling field has been discussed. We present
theoretical work on how this may be achieved in both Doppler systems, and
by extension in non-Doppler broadened systems. By considering the specific
example of atomic rubidium we demonstrate the feasibility and practical dif
ficulties of such an experiment. By considering systems with appropriate ro
tational-vibration structure we conclude that microwave induced transparenc
y in gas vapours is more readily achievable in molecular systems.