C. Duran et al., Fabrication and electrical properties of textured Sr0.53Ba0.47Nb2O6 ceramics by templated grain growth, J AM CERAM, 83(9), 2000, pp. 2203-2213
Textured Sr0.53Ba0.47Nb2O6 ceramics with a relative density of >95% were fa
bricated using templated grain growth (TGG), Acicular KSr2Nb5O15 template p
articles synthesized via a molten salt process were aligned by tape casting
in a mixture of solid-state-synthesized SrNb2O6 and BaNb2O6 powders. The r
esulting ceramics possessed strong fiber texture along the polar axis ([001
]) of the strontium barium niobate. Samples with 15.4 wt% templates attaine
d a textured fraction of 0.82 after sintering at a temperature of 1450 degr
ees C for 4 h. These materials showed peak dielectric constants of 7550 at
1 kHz, remanent polarizations of 13.2 mu C/cm(2), saturation polarizations
of 21 mu C/cm(2) (60%-85% of the single-crystal value), piezoelectric strai
n coefficients of 78 pC/N (70%-85% of the single-crystal value), and room-t
emperature pyroelectric coefficients of 2.9 x 10(-2) mu C-.(cm(2) (.)degree
s C)(-1) (52% of the single-crystal value). These results show that TGG is
a viable option for accessing single-crystal properties in polycrystalline
ceramics.