Synthesis of acyclic alpha- and beta-silyl sulfimides

Authors
Suslova, EN Kirpichenko, SV Albanov, AI Shainyan, BA
Citation
En. Suslova et al., Synthesis of acyclic alpha- and beta-silyl sulfimides, J CHEM S P1, (18), 2000, pp. 3140-3142
Citations number
26
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14704358 → ACNP
Issue
18
Year of publication
2000
Pages
3140 - 3142
Database
ISI
SICI code
1470-4358(2000):18<3140:SOAAAB>2.0.ZU;2-W
Abstract
Conversion of acyclic alpha- and beta-silyl sulfides by their treatment wit h sodium salts of N-chlorosulfonamides into the corresponding previously un known sulfimides is described. The process is accompanied by a competing re action resulting in the formation of alpha- or beta-silyl sulfoxides. beta- Silyl sulfimide (9b) undergoes thermolysis to generate trimethylvinylsilane .