P. Tabary et al., Effects of a low amount of C on the phase transformations in the AlN-Al2O3pseudo-binary system, J EUR CERAM, 20(12), 2000, pp. 1915-1921
The effects of a low amount of C on the phase transformations in the AlN-Al
2O3 pseudo-binary system are reported in samples having an AlN content in m
ol% ranging between 44 and about 0. Various complementary experimental tech
niques were used to determine the nature of the phase equilibria. Carbon is
embedded in the components of three eutectics as a function of the average
chemical composition of the sample in AlN. In two of them, a component bel
onging to the quaternary system Al-O-N-C and having a wide composition rang
e was found. Its X-ray and neutron diffraction spectra are well refined wit
h a hexagonal crystalline structure. (C) 2000 Elsevier Science Ltd. All rig
hts reserved.