We investigate the ground state properties of an S=1/2 distorted diamond ch
ain described by the Hamiltonian H = J(1) Sigma(l){((S) over right arrow(3l
-1) . (S) over right arrow(3l) + (S) over right arrow(3l) . (S) over right
arrow(3l+1)) + J(2)(S) over right arrow(3l-2) . (S) over right arrow(3l--1)
+ J(3) ((S) over right arrow(3l-2) . (S) over right arrow(3l) + (S) over r
ight arrow(3l) . (S) over right arrow(3l+2)) - HSlz} (J1, J2, J3 greater th
an or equal to 0), which models well a trimerized S=1/2 spin chain system C
u3Cl3(H2O)(2). 2H(3)C(4)SO(2). Using an exact diagonalization method by mea
ns of the Lanczos technique, we determine the ground state phase diagram in
the H=0 case, composed of the dimerized, spin fluid, and ferrimagnetic pha
ses. Performing a degenerate perturbation calculation, we analyze the phase
boundary line between the latter two phases in the J(2), J(3) much less th
an J(1) limit, the result of which is in good agreement with the numerical
result. We calculate, by use of the density matrix renormalization group me
thod, the ground state magnetization curve for the case (a) where J(1) = 1.
0, J(2) = 0.8, and J(3) = 0.5, and the case (b) where J(1) = 1.0, J(2) = 0.
8, and J(3) = 0.3. We find that in the case (b) the 2/3-plateau appears in
addition to the 1/3-plateau which also appears in the case (a). The transla
tional symmetry of the Hamiltonian H. is spontaneously broken in the 2/3-pl
ateau state as well as in the dimerized state.