The possibility to use thermal analysis for a quick characterisation of che
mical changes in the organic matter of composted materials was tested. Nine
samples were taken at progressive stages of maturation from the same trenc
h of a fully automated composting plant. DSC and TG were simultaneously per
formed in static air conditions on whole ground composts. Progressive stage
s in the composting process yielded samples whose DSC traces revealed appre
ciable modifications in thermal patterns that agreed well with quantitative
data obtained from TG measurements. The ratio between the mass losses asso
ciated with the two main exothermic reactions (R1) showed a good sensitivit
y in detecting the changes in the level of stabilisation during the compost
ing process. Thermal methods seem to be a valid comparative method in evalu
ating the level of bio-transformation of materials during a composting proc
ess.