New reactive polymeric stabilizers for emulsion polymerization

Authors
Tauer, K Zimmermann, A
Citation
K. Tauer et A. Zimmermann, New reactive polymeric stabilizers for emulsion polymerization, MACRO RAPID, 21(12), 2000, pp. 825-831
Citations number
31
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
21
Issue
12
Year of publication
2000
Pages
825 - 831
Database
ISI
SICI code
1022-1336(20000818)21:12<825:NRPSFE>2.0.ZU;2-W
Abstract
Partly sulfonated polyolefins represent very effective reactive stabilizers for heterophase polymerizations. For instance, under proper chosen conditi ons, the efficiency of these stabilizers in emulsion polymerization, measur ed in particle surface area stabilized per: gram surfactant, is higher than that for sodium dodecyl sulfate. H-1 NMR measurements prove that the stabi lizers will be almost completely covalently bound to the latex particles in the course of the polymerization.