The present study investigated whether effects of implicit learning (IL) ar
e due to well-learned and explicitly represented parts of the stimulus mate
rial ("chunks"). To this purpose, event-related brain potentials (ERPs) wer
e recorded during an oddball-version of a serial reaction time (RT) task: A
t unpredictable positions within a 16-item letter sequence, single deviant
items replaced an item of the repeatedly presented standard sequence. After
acquisition, the "process dissociation procedure" (Jacoby, 1991) was adopt
ed to identify explicitly learned sequence parts for each participant. Acqu
isition of sequence knowledge was reflected in faster RTs for standard item
s than for deviant items and in enhanced N2b and P3b components for deviant
items. While the ERP effects were obtained for explicitly represented sequ
ence parts only, RT effects were independent of subsequent reproduction per
formance. These results indicated that (1) ERPs are a valid measure of expl
icit knowledge, (2) implicit and explicit knowledge coexist in serial RT ta
sks, and (3) chunking processes play a major role in the acquisition of exp
licit knowledge about event sequences.