Dihydroazulene(DHA)/vinylheptafulvene(VHF) equilibration is based on photoc
hemical ring opening and thermal cyclization. Optical and non-linear optica
l properties of DHA/VHF are reported. Multimode switching, comprising both
photo-redox and off/on-fluorescence switching, are investigated. DHA covale
ntly attached to cellulose shows multifold switching. A concept for cyclic
multistate switching is proposed based on biphotochromic compounds.