(R)-Binaphthol-condensed benzofurylfulgide 3 was synthesized and its photoc
hromic properties as well as the change in other properties associated with
photochromism were investigated. Like its indole analogue 1, 3 showed dias
tereoselective photochromism. Change in CD spectra, on/off switching of flu
orescence, and reversible change in pitch length of induced cholesteric liq
uid crystalline phase, were observed.