Y. Inagaki et al., High-field magnetization and high-frequency ESR study on the tetranuclear cluster composed of pi-electrons (S=1/2) and d-electrons (S=5/2), MOLEC CRYST, 343, 2000, pp. 433-438
Recently, Iwamura's group has succeeded in synthesizing the interesting new
tetranuclear cluster composed of two paramagnetic Mn2+ ions (S=5/2 per ion
) and two organic free radicals (S=1/2 per radical) as bridging ligand, [{M
n(hfac)(2)}(2)(bnn)] (bnn=2,2'-bis[( 1-oxyl-3-oxide-4,4,5,5-tetramethyl-imi
dazolinyl)]). The crystal structure is triclinic (space group PI) and each
cluster is composed of two triangles which share their own base like a "but
terfly". There are two kind of exchange pathways within the cluster and bot
h of them are likely to be antiferromagnetic. Therefore, spin frustration m
ay occur and we expect many possible ground states with different total spi
ns (S-T=0 to S-T=6), depending on the relevant interactions and magnetic fi
eld.
We wish to discuss the important magnetic parameters such as exchange inter
actions and anisotropy which characterize this interesting system through m
easurements of high-field magnetization and high-frequency electron spin re
sonance.