Functionalized hyperbranched polyethylene powder supports

Citation
De. Bergbreiter et al., Functionalized hyperbranched polyethylene powder supports, ORG LETT, 2(18), 2000, pp. 2853-2855
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
18
Year of publication
2000
Pages
2853 - 2855
Database
ISI
SICI code
1523-7060(20000907)2:18<2853:FHPPS>2.0.ZU;2-C
Abstract
Polyethylene powders with useful loadings of functional groups are accessib le by hyperbranched grafting chemistry. Using a 200 mu m diameter high dens ity powder, loadings of up to 0.4 mmol/g of CO2H groups are attained. The c arboxylic acid groups in the resulting powders can be further functionalize d covalently or ionically and resulting powders have the physical durabilit y and solvent resistance associated with polyethylene itself.