Inter- and intramolecular reductive coupling reactions: An approach to thephorbol skeleton

Authors
Carroll, GL Little, RD
Citation
Gl. Carroll et Rd. Little, Inter- and intramolecular reductive coupling reactions: An approach to thephorbol skeleton, ORG LETT, 2(18), 2000, pp. 2873-2876
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
18
Year of publication
2000
Pages
2873 - 2876
Database
ISI
SICI code
1523-7060(20000907)2:18<2873:IAIRCR>2.0.ZU;2-4
Abstract
An expeditious convergent route to the ABC-tricyclic core of the phorbol es ters is described, The chemistry capitalizes upon both inter- and intramole cular reductive coupling processes promoted electrochemically and via the u se of samarium diiodide.