Progress toward the total synthesis of bafilomycin A(1): Stereoselective synthesis of the C15-C25 subunit by additions of nonracemic allenylzinc reagents to aldehydes
Ja. Marshall et Nd. Adams, Progress toward the total synthesis of bafilomycin A(1): Stereoselective synthesis of the C15-C25 subunit by additions of nonracemic allenylzinc reagents to aldehydes, ORG LETT, 2(18), 2000, pp. 2897-2900
A highly stereoselective synthesis of the C15-C25 subunit (2) of bafilomyci
n A(1) (1) has been accomplished by a route utilizing additions of chiral n
onracemic allenylzinc reagents to aldehydes.