The mixing efficiency of four alternative ozone dissolution systems, includ
ing conventional bubble diffusion and pipeline injection/diffusion reactors
, were compared by measuring the variability of ozone residual measurements
at the outlet of each reactor. The standard deviation and coefficient of v
ariation of a time series of residual measurements were used to provide a q
uantitative measure of the level of mixing in the reactor. The results indi
cate that properly designed pipeline dissolution systems provide significan
tly improved mixing over oxygen-fed or air-fed bubble diffusion systems. Mi
nimum mixing criteria for bubble diffusion systems cited in the literature
may underestimate the level of mixing required to achieve stable ozone resi
duals downstream of the dissolution chamber of conventional bubble diffusio
n chambers.