Ma. Anisimov et al., Experimental evidence for crossover to mean-field tricritical behavior in a concentrated salt solution, PHYS REV L, 85(11), 2000, pp. 2336-2339
We have discovered a mean-field multicritical point on the critical locus i
n an aqueous solution of 3-methylpyridine and sodium bromide. Light-scatter
ing measurements indicate Ising-like asymptotic critical behavior at the lo
wer salt concentrations. However, the temperature range of Ising critical b
ehavior shrinks with increasing salt concentration and the critical behavio
r becomes mean-field-like at a concentration of about 17% mass fraction of
NaBr. Emergence of a new characteristic length scale diverging at this poin
t and a simultaneous pronounced increase in the background scattering sugge
sts mean-field tricritical behavior associated with the formation of a micr
oheterogeneous phase due to clustering of ions and molecules.